Prof. Wu Guomin focusing on the national demand of low-carbon and emission reducing, and targeting the goals of green manufacturing for green materials, some achievements have been made in the waterborne and high-performance technologies for biomass based thermosetting polymers.
Proposing the mechanism of in-situ composite "cross-linking point like" enhancement of nanocellulose waterborne resin. By using active hydroxyl groups to form chemical coupling, the interaction between nanocellulose and resin matrix interface is enhanced, significantly improving the mechanical properties of the composite materials.
Developing the key technology for intramolecular self emulsification of biomass based epoxy resins. In view of the problem of poor storage stability of waterborne epoxy resin emulsion, the key technology of intramolecular self emulsification of epoxy resin was broken through, and the storage stability of emulsion was significantly improved from < 6 months of conventional products to > 18 months.
Developing the key technology for autocatalytic crosslinking of biomass based waterborne polyurethane. In response to the problem of slow film-forming speed of waterborne wood coatings, the key technology of self catalytic crosslinking of waterborne polyurethane was broken through, and the film-forming speed of the coating at room temperature was shortened from 7 days to 3 days.
Creating and applying new waterborne thermosetting resin for high-end wood coatings. A new generation of waterborne thermosetting resin cured with silane coupling agents with epoxy groups was developed using the compatibility mechanism of organic silicon. The product supports thick wet film coating, and the coating has outstanding performance advantages such as high fullness, high glossiness, high hardness, and high chemical resistance.
Green manufacturing and flame retardant enhancement mechanism of wood fiber composite materials modified with deep eutectic solvents, Fundamental research funds of Jiangsu Key Lab. of Biomass Energy and Material, 2023 to 2025, ￥200000Yuan, Principal of the project.
Manufacturing technology of waterborne epoxy resin emulsion, Contract of technical achievement transformation, 2021 to 2021, ￥1200000Yuan, Principal of the project.
Study on the UV curing activity control and properties of waterborne epoxy itaconic acid ester resin, Sub project of the international cooperation project funded by the Fundamental Research Funds for the Central Nonprofit Research Institution of Chinese Academy of Forestry, 2020 to 2023,￥500000Yuan, Principal of the Sub project.
Precise dissociation and interface regulation of wood fibers, Subtask of the major project of the National Natural Science Foundation of China, 2019 to 2012, ￥334000Yuan, Principal of the Subtask.
Mechanism of performance control and autocatalytic crosslinking characteristics response of rosin based two component waterborne polyurethane, General project of Natural Science Foundation of Jiangsu Province, 2019 to 2022, ￥100000Yuan, Principal of the project.
Manufacturing and application technology of biomass based waterborne polyurethane for wood coatings, Key project funded by the Fundamental Research Funds for the Central Nonprofit Research Institution of Chinese Academy of Forestry, 2016 to 2019, ￥1500000Yuan, Principal of the project.
Preparation and properties of thermosetting waterborne PU/CNF nanocomposite polymers, Fundamental research funds of Jiangsu Key Lab. of Biomass Energy and Material, 2015 to 2017,￥100000Yuan, Principal of the project.
Study on the microstructure and properties of thermosetting nanopolymer materials prepared by waterborne terpene based resin compositing with CNW, Project of the National Natural Science Foundation of China, 2012 to 2014, ￥230000Yuan, Principal of the project.
Technical research and development of biomass based waterborne epoxy resin, Key project funded by the Fundamental Research Funds for the Central Nonprofit Research Institution of Chinese Academy of Forestry, 2007 to 2010,￥2350000Yuan, Principal of the project.
Zhan Xun, Chen Jian, Yang Zhaozhe, Wu Guomin*, Kong Zhenwu. Superhydrophobic film from silicone-modified nanocellulose and waterborne polyurethane through simple sanding process. 2023. International Journal of Biological Macromolecules, 232: 123431.
Wu Guomin*, Chen Jian, Yang Zhaozhe, Jin Can, Liu Guifeng, Huo Shuping, Kong Zhenwu*. Preparation and properties of autocatalytic biobased waterborne polyol from rosin based epoxy resin. 2022. Journal of Polymers and the Environment, 30: 3340-3350.
Wu Guomin*, Bian Junna, Liu Guifeng, Chen Jian, Huo Shuping, Jin Can, Kong Zhenwu*. Self-catalytic two-component waterborne polyurethanes with amino polyols from biomass based epoxy resin. 2020. Journal of Polymers and the Environment, 28:713-724.
Wu Guomin, Liu Di, Chen Jian, Liu Guifeng, Kong Zhenwu*. Preparation and properties of super hydrophobic films from siloxane-modified two-component waterborne polyurethane and hydrophobic nano SiO2. 2019. Progress in Organic Coatings, 127:80-87.
Wu Guomin, Li Qian, Jin Can, Kong Zhenwu*, Wang Siqun*. Characterization of the redispersibility of cellulose nanocrystals by particle size analysis using dynamic light scattering. 2019. Tappi Journal, 18:223-231.
Wu Guomin, Feng Xinhao, Jin Can, Kong Zhenwu*, Wang Siqun*. Effect of lignin-containing cellulose nanofibrils on the curing kinetics of polymeric diphenylmethane diisocyanate resin. 2019. Holzforschung, 73:879-887.
Wu Guomin*, Liu Guifeng, Chen Jian, Kong Zhenwu*. Preparation and properties of thermoset composite films from two-component waterborne polyurethane with low loading level nanofibrillated cellulose. 2017. Progress in Organic Coatings, 106: 170-176.
Wu Guomin*, Liu Di, Liu Guifeng, Chen Jian, Huo Shuping, Kong Zhenwu*. Thermoset nanocomposites from waterborne bio-based epoxy resin and cellulose nanowhiskers. 2015, Carbohydrate Polymers, 127: 229-235.
Wu Guomin*, Chen Jian, Huo Shuping, Liu Guifeng, Kong Zhenwu. Thermoset nanocomposites from two-component waterborne polyurethanes and cellulose whiskers. 2014. Carbohydrate Polymers, 105: 207-213.
Wu Guomin*, Kong Zhenwu*, Chen Jian, Huo Shuping, Liu Guieng. Preparation and properties of waterborne polyurethane/epoxy resin composite coating from anionic terpene-based polyol dispersion. 2014. Progress in Organic Coatings, 77: 315-321.
Wu Guomin*, Kong Zhenwu*, Chen Caifeng, Chen Jian, Huo Shuping, Jiang Jianchun. Kinetics of the crosslinking reaction of nonionic polyol dispersion from terpene-maleic ester type epoxy resin. 2013. Journal of Thermal Analysis and Calorimetry, 111: 735-741.
Wu Guomin, Kong Zhenwu*, Chen Caifeng, Chen Jian, Huo Shuping, Jiang Jianchun. Evaluation of the crosslinking reaction kinetics of cationic polyol dispersions with differential scanning calorimetry and dielectric analysis. 2013. Thermochimica Acta, 551: 118-123.
Wu Guomin*, Kong Zhenwu*, Chen Jian, Huo Shuping, Jiang Jianchun. Crosslinking reaction and properties of two-component waterborne polyurethane from terpene-maleic ester type epoxy resin. 2013. Journal of Applied Polymer Science, 128:132-138.
Wu Guomin*, Kong Zhenwu*, Chen Jian, Jiang Jianchun. Preparation and properties of nonionic polyol dispersion from terpinene-maleic ester-type epoxy resin. 2011. Journal of Applied Polymer Science, 120:579-585.
Wu Guomin, Kong Zhenwu*, Huang Huan, Chen Jian, Chu Fuxiang. Synthesis, characterization and properties of polyols from hydrogenated terpinene-maleic ester type epoxy resin. 2009. Journal of Applied Ploymer Science, 2009, 113: 2894-2901.
Wu Guomin, Bian Junna, Kong Zhenwu, Chen Jian, Yang Zhaozhe. Preparation method of waterborne epoxy itaconic ester resin with high UV curing activity: CN202110684611.2. 2023-6-30.
Wu Guomin, Bian Junna, Kong Zhenwu, Chen Jian, Yang Zhaozhe. Preparation method of waterborne dispersion of organic silicon modified epoxy itaconic ester resin: CN202110685072.4. 2022-3-8.
Wu Guomin, Kong Zhenwu, Chen Jian. A two-step method for preparing waterborne epoxy resin dispersion: CN202110214043.X. 2021-12-24.
Wu Guomin, Kong Zhenwu, Chen Jian, Liu Guifeng. Highly compatible waterborne polyol dispersion from organosilicon modified epoxy resin, and its preparation method: CN2019112812455. 2021-11-12.
Wu Guomin, Kong Zhenwu, Chen Jian, Liu Guifeng. Two-component waterborne polyurethane composited with cellulose nanofiber, and its preparation method and application: CN201610157014.3. 2018-12-21.
Wu Guomin, Liu Di, Kong Zhenwu. Anionic waterborne polyol dispersion from polysiloxane modified terpene based epoxy resin, and its preparation method: CN201510750106.8. 2018-5-15.
Wu Guomin, Liu Di, Kong Zhenwu. Superhydrophobic self-cleaning polymer from polysiloxane modified waterborne terpene based EP/PU composited with nano SiO2, and its preparation method: CN201610609794.0. 2018-7-6.
Wu Guomin, Kong Zhenwu, Chen Jian, Huo Shuping, Liu Guifeng. Waterborne epoxy resin composited with Cellulose nanocrystals, and its preparation method: CN201410407959.7. 2017-01-18.
